1,4-Dioxane has been identified as a "contaminant of emerging concern" following its detection in drinking water sources internationally. In Sweden, the substance has received limited attention and has been analyzed to a small extent. 1,4-Dioxane has been used as an additive in 1,1,1-trichloroethane (TCA) and trichloroethylene (TCE).
The aim of the investigation was to map the potential presence of 1,4-dioxane in areas contaminated with TCA and/or TCE in Sweden, and to examine the concentrations at which the substance occurs.
The goal was to assess whether there may be a need to include 1,4-dioxane in the investigation of such areas in Sweden.
Nine sites were selected for the study: four with confirmed contamination by both TCA and TCE, and five with TCE only.
1,4-Dioxane was detected in groundwater at six of the nine sites. In surface water samples, 1,4-dioxane was not detected at any location. The reporting limit for 1,4‑dioxane varied between 0.07 and 2 µg/L. The highest concentrations of 1,4-dioxane at each of the sites contaminated with both TCA and TCE ranged between 11.9 and 105 µg/L.
The investigations indicate a clear correlation between TCA and 1,4-dioxane, and a weaker correlation between TCE and 1,4-dioxane.
Based on the results, it is recommended that 1,4-dioxane be included in the investigation of areas contaminated with TCA. For areas contaminated with TCE, it is generally not considered justified to investigate the presence of 1,4-dioxane, but it may be relevant in certain cases, such as in proximity to drinking water wells.